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Beilstein J. Org. Chem. 2015, 11, 1017–1022, doi:10.3762/bjoc.11.114
Graphical Abstract
Scheme 1: Described synthesis of cyclopentenone 4 using a combination of Mo(VI) and Au(I)-catalyzed reactions...
Scheme 2: The Rautenstrauch rearrangement.
Scheme 3: Synthesis of 1-styrylpropargyl alcohols.
Scheme 4: Postulated mechanism for the formation of cyclopentenone 4 and furan 13 (entry 1, Table 1; An= p-anisyl).
Scheme 5: Proposed mechanism for the formation of enone 19.
Scheme 6: Rearrangement of unprotected propargylic carbinol 27.